Corrosion aspects of alkyd paints modified with linseed and soy oils

Abstract

The anticorrosive performance of medium-long (54–59%) alkyd paints modified with linseed and soy oils was compared by accelerated tests (Prohesion Cycle) and natural exposition in marine and industrial atmospheres. Differences on the protection mechanism of anticorrosive pigments due to substitution of linseed oil by soy oil were investigated by polarization curves and electrochemical impedance spectroscopy (EIS). Complementary tests such as water vapor and ions permeability in freestanding films were also performed. Results suggested that the type of oil influenced the barrier properties of the paint pigmented with zinc phosphate. The same tendency was verified by resistance values obtained from impedance diagrams. Polarization curves suggest that the action of the pigments in the alkyd paintings is practically the same for both oils. The substitution of linseed oil by soy oil did not impair the anticorrosive performance of alkyd paints and from the economic point of view this substitution could be very interesting.