Kinetic modeling of anaerobic carboxylic acid production from swine wastewater

Abstract

This work aimed to evaluate the potential of anaerobic carboxylic acids (CA) production from swine wastewater (SW), perform modeling studies of the acidogenic process and estimate the kinetic parameters. Tests were carried out in four batch reactors with 250 mL reaction volume, with brewery sludge as inoculum and using chloroform (0.05%, v/v) for methanogenesis inhibition. Hydrolysis was the main limiting step of CA production from SW, once that it took more than twenty days for the particulate COD consumption to stabilize and fourteen days to produce 60% of the acids formed. A yield of 0.33 mg mgCODA−1, corresponding to 0.40 mgCOD mgCODA−1, was obtained. Kinetic models describing logistic growth functions were best suited to simulate CA production.