Organic and isotopic geochemistry of evaporites and shales of the Santana Group (Araripe Basin, Brazil): clues on the evolution of depositional systems and global correlation during the lower cretaceous

Abstract

Even being the more studied of the interior basins of Northeast Brazil, the Araripe Basin still lacks research in organic geochemistry designed to support interpretations of depositional systems and conditions of formation. This work aims to investigate the organic behavior of evaporites and shales from the Santana Group (Lower Cretaceous), as well as discuss their role in the evolution of its depositional systems. A total of 23 samples, 17 shales and six evaporites, were collected in outcrops and quarries. Analyses of Total Organic Carbon (TOC), Total Sulfur (TS), Rock Eval pyrolysis, and the δ34S isotope ratio were performed. The TOC results revealed high organic content for seven intervals, of which only five had high TS content. From the Rock Eval pyrolysis, dominance of the Type I kerogen was verified, thus corresponding to the best type of organic matter (mainly algal) for the generation of liquid and gaseous hydrocarbons. The Lower Cretaceous (probably Aptian) response to the progressive evolution in redox conditions is linked to a remarked Oceanic Anoxic Event (OAE-1a). The TOC/TS ratio suggests variable palaeosalinity, indicating most of the shales were formed under brackish waters with saline influence, yet tending to increase the salinity upwards where hypersaline conditions dominate in the Ipubi Formation. The isotope data also suggest the occurrence of marine ingressions in the depositional systems even prior to the well-documented event of the Romualdo Formation.