Relevance of the physicochemical properties of calcined quail eggshell (CaO) as a catalyst for biodiesel production

Abstract

The CaO solid derived from natural quail eggshell was calcined and employed as catalyst to produce biodiesel via transesterification of sunflower oil. The natural quail eggshell was calcined at 900∘C for 3 h, in order to modify the calcium carbonate present in its structure in CaO, the activity phase of the catalyst. Both precursor and catalyst were characterized using Hammett indicators method, X-ray fluorescence (XRF), X-ray diffraction (XRD), thermogravimetric analysis (TG/DTG), CO2 temperature programmed desorption (CO2-TPD), X-ray photoelectronic spectroscopy (XPS), Fourier infrared spectroscopy (FTIR), scanning electron microscopy (SEM),N2 adsorption-desorption at −196∘C, and distribution particle size.Themaximumbiodiesel production was of 99.00 ± 0.02wt.% obtained in the following transesterification reaction conditions: Xₘᵣ (sunflower oil/methanolmolar ratio of 1 : 10.5 mol : mol), Xⅽₐₜ (catalyst loading of 2wt.%), Xᵼᵢₘₑ (reaction time of 2 h), stirring rate of 1000 rpm, and temperature of 60∘C.